5. E. Szafoni, D. Lewandowski, M. Gruszczyński, K. Broniarz, H. Stachowiak-Dluzyńska, K. Kuciński and G. Hreczycho, Streamlining Si-O Bond Formation Through Cobalt-Catalyzed Dehydrocoupling, Chem. Commun. 2024, in press
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This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
4. D. Lewandowski and G. Hreczycho,Cobalt-Catalyzed Reduction of Aldehydes to Alcohols via the Hydroboration Reaction, Int. J. Mol. Sci. 2024, 25(14), 7894
doi:10.3390/ijms25147894
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
3. E. Szafoni, K. Kuciński and G. Hreczycho, Cobalt-Driven Cross-Dehydrocoupling of Silanes and Amines for Silylamine Synthesis, ChemCatChem 2024, 16, e202400143
doi:10.1002/cctc.202400143
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
2. D. Lewandowski and G. Hreczycho,Selective Hydrosilylation and Hydroboration of Allenes Catalyzed by Cobalt-Pincer Complexes, Adv. Synth. Catal. 2024, 366, 2775-2783
doi:10.1002/adsc.202400309
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
1. H. Stachowiak-Dluzyńska, M. Gruszczyński, M. Kubicki and G. Hreczycho, Pt(II) Complexes Bearing P,N-donor Ligands as Catalysts in Chemoselective Hydrosilylation, Hydrogermylation, and Hydroboration of Terminal Alkenes, J. Catal. 2024, 433, 115494
doi:10.1016/j.jcat.2024.115494.
7. K. Broniarz and G. Hreczycho, Access to Unsaturated Organogermanes via (De)hydrosilylation Mediated by Cobalt Complexes, Org. Lett. 2023, 25, 6528-6533,
doi:10.1021/acs.orglett.3c02326.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
6. H. Stachowiak-Dluzyńska and G. Hreczycho, Co-catalyzed hydrosilylation of ketones under base-free conditions: a convenient route to silyl ethers or secondary alcohols, ChemCatChem 2023, 15, e202300781
doi:10.1002/cctc.202300781.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
5. H. Stachowiak-Dluzyńska, K. Kuciński, B. Wyrzykiewicz, R. Kempe and G. Hreczycho, Co-catalyzed Selective syn-Hydrosilylation of Internal Alkynes, ChemCatChem 2023, 15, e202300592
doi:10.1002/cctc.202300592.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
4. K. Kuciński, A. Luczak, A. Mankouski and G. Hreczycho, Base-catalyzed addition of silylacetylenes to ketones: a route to protected tertiary propargyl alcohols, Org. Chem. Front. 2023, 10, 2752-2759.
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3. D. Lewandowski and G. Hreczycho, Cobalt pincer-type complexes demonstrating unique selectivity for hydroboration reaction of olefin under mild conditions, Inorg. Chem. Front. 2023, 10, 3656-3663.
doi:10.1039/D3QI00478C.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
2. E. Szafoni, K. Kuciński and G. Hreczycho, Cobalt-Catalyzed Dehydrogenative Cross-Coupling Reaction: Selective Access to Dihydrosiloxanes, Hydrosiloxanes and Functionalized Silsesquioxanes, J. Catal. 2023, 423, 1-9.
doi:10.1016/j.jcat.2023.04.013.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
1. H. Stachowiak-Dluzyńska, K. Kuciński, K. Broniarz, E. Szafoni, M. Gruszczyński, D. Lewandowski, G. Consiglio and G. Hreczycho, Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species , Sci. Rep. 2023, 13, 5618
doi:10.1038/s41598-023-32172-9.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
8. E. Szafoni, K. Kuciński and G. Hreczycho, Cobalt-Catalyzed Synthesis of Silyl Ethers via Cross-Dehydrogenative Coupling Between Alcohols and Hydrosilanes, Green Chem. Rev. Lett. 2022, 15, 757-764
doi:10.1080/17518253.2022.2133554.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
7. K. Kuciński and G. Hreczycho, Silicon-Nitrogen Bond Formation via Dealkynative Coupling of Amines with Bis(trimethylsilyl)acetylene Mediated by KHMDS, Chem. Commun. 2022, 58, 11386-11389
doi:10.1039/D2CC04413G.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
6. K. Kuciński, M. Gruszczyński, and G. Hreczycho, Ru-catalyzed Formation of Thiosilanes and Selenosilanes using Dichalcogenides as a User-Friendly Alternative to Thiols and Selenols, ChemCatChem 2022, 14, e202200961
doi:10.1002/cctc.202200961.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
5. D. Lewandowski, T. Cytlak, R. Kempe and G. Hreczycho, Ligand-controlled Cobalt-Catalyzed Formation of Carbon-Boron Bonds: Hydroboration vs. C-H/B-H Dehydrocoupling, J. Catal. 2022, 413, 728-734
doi:10.1016/j.jcat.2022.07.037.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
4. K. Kuciński and G. Hreczycho, Transition metal-free catalytic C-H silylation of terminal alkynes with bis(trimethylsilyl)acetylene initiated by KHMDS, ChemCatChem 2022, 14, e202200794
doi:10.1002/cctc.202200794.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
3. K. Kuciński, H. Stachowiak-Dluzyńska and G. Hreczycho, Catalytic Silylation of O-Nucleophiles via Si-H or Si-C Bond Cleavage: A Route to Silyl Ethers, Silanols and Siloxanes, Coord. Chem. Rev. 2022, 459, 214456
doi:10.1016/j.ccr.2022.214456.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
2. K. Kuciński, H. Stachowiak-Dluzyńska, D. Lewandowski, M. Gruszczyński, P. Lampasiak, and G. Hreczycho, A Review of The R3Si-NH-SiR3-Type Disilazanes: From Synthesis to Applications, J. Organomet. Chem. 2022, 961, 122127
doi:10.1016/j.jorganchem.2021.122127.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
1. H. Stachowiak-Dluzynska, K. Kuciński, F. Kallmeier, R. Kempe and G. Hreczycho, Cobalt-Catalyzed Dehydrogenative C-H Silylation of Alkynylsilanes, Chem. Eur. J. 2022, 28, e202103629
doi:10.1002/chem.202103629.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
1. M. Nowicki, K. Kuciński, G. Hreczycho and M. Hoffmann, Catalytic and Non-Catalytic Hydroboration of Carbonyls: The Quantum-Chemical Studies, Org. Biomol. Chem. 2021, 19, 3004-3015
doi:10.1039/D1OB00037C.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
5. K. Kuciński, H. Stachowiak and G. Hreczycho, Silylation of Silanols with Hydrosilanes via Main-Group Catalysis: The Synthesis of Unsymmetrical Siloxanes and Hydrosiloxanes, Inorg. Chem. Front. 2020, 7, 4190-4196
doi:10.1039/D0QI00904K.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
4. K. Kuciński and G. Hreczycho, Hydrosilylation and hydroboration in a sustainable manner: from Earth-abundant catalysts to catalyst-free solutions , Green Chem. 2020, 22, 5210-5224.
doi:10.1039/D0GC01430C.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
3. K. Kuciński, H. Stachowiak and G. Hreczycho, Silylation of Alcohols, Phenols, and Silanols with Alkynylsilanes - an Efficient Route to Silyl Ethers and Unsymmetrical Siloxanes, Eur. J. Org. Chem. 2020, 2020, 4042-4049.
doi:10.1002/ejoc.202000573.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
2. J. Kaźmierczak, D. Lewandowski and G. Hreczycho, B(C6F5)3-catalyzed dehydrocoupling of POSS silanols with hydrosilanes - a metal-free strategy for effecting functionalization of silsesquioxanes, Inorg. Chem. 2020, 59, 13, 9206-9214.
doi:10.1021/acs.inorgchem.0c01125.
This work was supported by the Polish National Science Center, grant: UMO-2017/27/N/ST5/00091
1. K. Kuciński and G. Hreczycho, Potassium Fluoride-Catalyzed Hydroboration of Aldehydes and Ketones: Facile Reduction to Primary and Secondary Alcohols, Eur. J. Org. Chem. 2020, 2020, 5, 552-555.
doi:10.1002/ejoc.201901514.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
Featured in Org. Chem. Highlights: Reduction
7. J. Kaźmierczak and G. Hreczycho, Highly Effective Functionalization of Silsesquioxanes Mediated by Inexpensive Earth-Abundant Metal Catalyst - Potassium tert-Butoxide, J. Catal. 2019, 378, 90-96.
doi: 10.1016/j.jcat.2019.08.022.
This work was supported by the Polish National Science Center, grant: UMO-2017/27/N/ST5/00091
6. J. Kaźmierczak and G. Hreczycho, Copper(II) Triflate-Mediated Synthesis of Functionalized Silsesquioxanes via Dehydrogenative Coupling of POSS Silanols with Hydrosilanes, Dalton Trans. 2019, 48, 6341-6346.
doi: 10.1039/C9DT01135H.
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
5. A. Walczak, H. Stachowiak, G. Kurpik, J. Kaźmierczak, G. Hreczycho and A. Stefankiewicz, High catalytic activity and selectivity in hydrosilylation of new Pt(II) metallosupramolecular complexes based on ambidentate ligands, J. Catal. 2019, 373, 139-146.
doi:10.1016/j.jcat.2019.03.041
4. K. Kuciński and G. Hreczycho, Lithium Triethylborohydride as Catalyst for Solvent-Free Hydroboration of Aldehydes and Ketones, Green Chem. 2019, 29, 1912-1915.
doi:10.1039/C9GC00216B.
This work was supported by the Polish National Science Center, grant: UMO-2018/30/E/ST5/00045
2. J. Kaźmierczak, K. Kuciński, D. Lewandowski and G. Hreczycho, Ru-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes - Its Introduction To One-Pot Synthesis, Inorg. Chem. 2019, 58, 1201-1207.
doi:10.1021/acs.inorgchem.8b02645
This work was supported by the Polish National Science Center, grant: UMO-2017/27/N/ST5/00091
1. K. Kuciński and G. Hreczycho, A Highly Effective Route to Si-O-Si Moieties through O-Silylation of Silanols and Polyhedral Oligomeric Silsesquioxane Silanols with Disilazanes, ChemSusChem 2019, 12, 1043-1048.
doi:10.1002/cssc.201802757.
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
8. K. Bartkowiak, G. Consiglio and G. Hreczycho, The Synthesis of Novel Bifunctional Silanes Containing Ester Groups, Curr. Org. Chem. 2018, 22, 24, 2413-2417
doi:10.2174/1385272822666181024125042.
This work was supported by the Polish National Science Center, grant: UMO-2013/09/B/ST5/00293
7. J. Kaźmierczak and G. Hreczycho, Nafion as effective and selective heterogeneous catalytic system
in O-metalation of silanols and POSS silanols, J. Catal. 2018, 367, 95-103
doi:10.1016/j.jcat.2018.08.024.
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
6. K. Kuciński, M. Jankowska-Wajda, T. Ratajczak, S. Balabanska-Trybus, A. Schulmann, H. Maciejewski, M. K. Chmielewski and G. Hreczycho, Silica Surface Modification and its Application in Permanent Link with Nucleic Acids, ACS Omega 2018, 3, 6, 5931-5937,
doi:10.1021/acsomega.8b00547.
This work was supported by the Polish National Science Center, grant: UMO-2013/09/B/ST5/00293
5. K. Kuciński and G. Hreczycho, S-Acetylation of thiols mediated by triflic acid: a novel route to thioesters, Org. Process Res. Dev. 2018, 22, 4, 489-493,
doi:10.1021/acs.oprd.7b00378.
This work was supported by the Polish National Science Center, grants: UMO-2015/19/B/ST5/00240 and UMO-2017/24/T/ST5/00130
4. H. Stachowiak, J. Kaźmierczak, K. Kuciński and G. Hreczycho, Catalyst-Free and Solvent-Free Hydroboration of Aldehydes, Green Chem. 2018, 20, 1738-1742,
doi: 10.1039/C8GC00042E.
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
3. J. Langer and G. Hreczycho, Pseudo-enantiomeric chiral components and formation
the helical micro- and nanostructures in CT complexes , Royal Soc. Open Sci. 2018, 5(3): 171499,
doi:10.1098/rsos.171499.
2. K. Kuciński and G. Hreczycho, Diisopropylamine as a single catalyst in the synthesis of aryl disulfides, Green Process. Synth. 2018, 7, 1, 12-15,
doi:https://doi.org/10.1515/gps-2016-0205.
This work was supported by the Polish National Science Center, grant: UMO-2014/15/N/ST5/00595
1. J. Kaźmierczak, K. Kuciński, H. Stachowiak and G. Hreczycho, Introduction of Boron Functionalities into Silsesquioxanes - Novel Independent Methodologies, Chem. Eur. J. 2018, 24, 2509–2514,
doi:10.1002/chem.201705898.
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
8. K. Kuciński and G. Hreczycho, Chemoselective and catalyst-free O-borylation of silanols: a facile access to borasiloxanes, ChemSusChem 2017, 10, 4695–4698,
doi:10.1002/cssc.201701648
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
7. J. Kaźmierczak and G. Hreczycho, Catalytic Approach to Germanium-functionalized
Silsesquioxanes and Germasilsesquioxanes, Organometallics 2017, 36, 19, 3854-3859,
doi:10.1021/acs.organomet.7b00599.
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
6. K. Kuciński and G. Hreczycho, Highly Efficient and Chemoselective Tertiary and Secondary Benzylation of Thiols Catalyzed by Indium(III) Triflate, Eur. J. Org. Chem. 2017, 5572-5581,
doi:10.1002/ejoc.201701007.
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
5. J. Kaźmierczak, K. Kuciński and G. Hreczycho, Highly Efficient Catalytic Route for the Synthesis of Functionalized Silsesquioxanes, Inorg. Chem. 2017, 56, 9337-9342,
doi:10.1021/acs.inorgchem.7b01504.
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
4. K. Kuciński and G. Hreczycho, Ruthenium-catalyzed hydrosilylation of C=N bond in benzothiazole, J. Organomet. Chem. 2017, 846, 321-325,
doi:10.1016/j.jorganchem.2017.07.007.
This work was supported by the Polish National Science Center, grants: UMO-2014/15/N/ST5/00595 and UMO-2013/09/B/ST5/00293
3. K. Kuciński and G. Hreczycho, Catalytic Formation of Silicon-Heteroatom (N, P, O, S) Bonds, ChemCatChem 2017, 9, 1868-1885,
doi:10.1002/cctc.201700054.
This work was supported by the Polish National Science Center, grant: UMO-2015/19/B/ST5/00240
2. K. Kuciński and G. Hreczycho, Synthesis of novel bifunctional organosilicon dendrons via platinum-catalyzed hydrosilylation, Inorg. Chim. Acta 2017, 461, 233-238,
doi:10.1016/j.ica.2017.02.029.
This work was supported by the Polish National Science Center, grant: UMO-2014/15/N/ST5/00595
1. J. Kaźmierczak, K. Kuciński, J. Szudkowska-Frątczak and G. Hreczycho, Highly Efficient Synthesis of Boron- and Germanium-Substituted Unsymmetrical Disilazanes, Eur. J. Inorg. Chem. 2017, 2017, 1888-1891,
doi:10.1002/ejic.201700083.
This work was supported by the Polish National Science Center, grant: UMO-2013/09/B/ST5/00293
3. K. Kuciński and G. Hreczycho, Highly Efficient One-Step Synthesis of N-Trimethylsiloxy Alkyl Imidothioates, Eur. J. Org. Chem. 2016, 2016, 4577-4585,
doi:10.1002/ejoc.201600768.
This work was supported by the Polish National Science Center, grant: UMO-2014/15/N/ST5/00595
2. K. Kuciński, J. Szudkowska-Frątczak and G. Hreczycho, Pt-Catalyzed Synthesis of Functionalized Symmetrical and Unsymmetrical Disilazanes, Chem. Eur. J. 2016, 22, 13046-13049,
doi:10.1002/chem.201602625.
This work was supported by the Polish National Science Center, grant: UMO-2013/09/B/ST5/00293
1. K. Kuciński, L. Wiśniewska and G. Hreczycho, Synthesis of Aryl Disulfides by Bismuth(III) Triflate-Mediated Coupling of Thiols, Curr. Org. Chem. 2016, 20, 1345-1349,
doi:10.2174/1385272820666151228192157.
This work was supported by the Polish National Science Center, grant: UMO-2014/15/N/ST5/00595
8. K. Kuciński, P. Pawluć and G. Hreczycho, Scandium(III) Triflate-Catalyzed anti-Markovnikov Hydrothiolation of Functionalized Olefins, Adv. Synth. Catal. 2015, 357, 3936-3942,
doi:10.1002/adsc.201500720.
This work was supported by the Polish National Science Center, grant: UMO-2013/09/B/ST5/00293
7. J. Szudkowska-Frątczak, B. Marciniec, G. Hreczycho, M. Kubicki and P. Pawluć, Ruthenium-Catalyzed Silylation of 1,3-Butadienes with Vinylsilanes, Org. Lett. 2015, 17, 2366-2369,
doi:10.1021/acs.orglett.5b00865.
6. J. Szudkowska-Frątczak, G. Hreczycho and P. Pawluć,Silylative coupling of olefins with vinylsilanes in the synthesis of functionalized alkenes, Org. Chem. Front. 2015, 2, 730-738,
doi:10.1039/C5QO00018A.
5. J. Szudkowska-Frątczak, M. Zaranek, G. Hreczycho, M. Kubicki, T. Grabarkiewicz, P. Pawluć, A silicon-assisted synthesis of (E)-B-haloenamides from N-vinylamides, Appl. Organometal. Chem. 2015, 29, 270-275,
doi:10.1002/aoc.3284.
4. G. Hreczycho, E. Frydrych-Tomczak, K. Sterzynska, J. Budna, A. Malinska, H. Maciejewski, M. Zabel, Novel organosilicon dendrons as effective linkers for biomolecules binding on a glass surface, Appl. Organometal. Chem. 2015, 29, 216-220,
doi:10.1002/aoc.3272.
3. K. Kuciński, P. Pawluć and G. Hreczycho, Metal triflate-mediated coupling of allylgermanes with thiols: a facile route to thiogermanes, Dalton Trans. 2015, 44, 10943-10946,
doi:10.1039/C5DT01734C.
This work was supported by the Polish National Science Center, grant: UMO-2013/09/B/ST5/00293
2. G. Hreczycho, An Efficient Catalytic Approach for the Synthesis of Unsymmetrical Siloxanes, Eur. J. Inorg. Chem. 2015, 1, 67-72,
doi:10.1002/ejic.201402904.
This work was supported by the Ministry of Science and Higher Education (Poland), grant: IP2011 017771
1. K. Kuciński, P. Pawluć, B. Marciniec and G. Hreczycho, Highly Selective Hydrothiolation of Unsaturated Organosilicon Compounds Catalyzed by Scandium(III) Triflate, Chem. Eur. J. 2015, 21, 4940-4943,
doi:10.1002/chem.201406412.
This work was supported by the Polish National Science Center, grant: UMO-2013/09/B/ST5/00293